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close proximity in both energy and real space of levels 11) and |2). A more general observation, from comparing Figs 9.43 with 9.44, shows that the electron electron scattering rate out of level |2) is very much faster than that due to scattering with LO phonons. In addition, it is also apparent that in both cases the depopulation rate is larger then the repopulation rate, and hence a population inversion is likely. This is confirmed by Fig. 9.45, which plots the ratio of the lifetimes a simple quantity which has been shown to approximate the population ratio between levels |3) and |2). Thus, in conclusion, using the methods outlined, this active-layer design has been shown to exhibit a population inversion between levels |3) and |2) at 77 K. The corresponding emission energy, given by the subband separation E3 E2, varies between 33 and 53 meV, which, in turn, correspond to 37 and 23 hm, respectively. Electroluminescence has been observed at 88 hm in a quantum cascade device at low temperatures [219]. 9.23 CARRIER SCATTERING IN QUANTUM WIRES AND DOTS Carrier scattering in lower-dimensional systems, wires and dots, will be an important issue as they are introduced into future generations of opto-electronic devices. For the theoretical understanding of the carrier dynamics, scattering rate expressions will be needed. Although the scattering rates derived here are not applicable to such systems, the techniques employed to obtain them do have some relevance. Quantum wires resemble quantum wells more closely than dots, as they still retain carrier dispersion. Therefore developing a model of carrier scattering with bulk LO phonons will require expressing the carrier wave function as a product of a two-dimensional envelope
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Figure 9.45 The ratio of the lifetimes T32/t21 of electrons in the triple quantum well active region of the quantum cascade laser
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function with a one-dimensional plane wave, as opposed to the other way around. The remainder of the derivation should follow in a similar fashion. Similar arguments for the route to carrier carrier scattering in quantum wires may also be applicable. However, for quantum dots the situation is quite different as the carriers never possess dispersion; hence, for scattering with phonons of fixed energies, it would appear a priori that this will only occur for resonance conditions, i.e. when the sublevel separation is equal to a phonon energy. Carrier carrier scattering between the sublevels of quantum dots resembles the Coulomb interaction in multi-electron atoms, with the latter being an area where much work has been done. Theoretical, and hence computational studies of carrier scattering in quantum wires and dots are still quite rare in the literature, although see for example [220-225]. For an introduction to some aspects of the particulars of optical processes (carrier-photon scattering) in wires and dots see Basu ([11], p. 343).
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